Supergénny jarosit v metalydite na lokalite Betliar-Turecká (Slovenská republika)
Roč.31,č.1-2(2024)
Jarosite was identified for the first time in the metalydite of the Bystrý potok Formation of
the Gelnica Group in the Southern Gemeric Unit of the Western Carpathians (Slovakia) at
the locality Betliar-Turecká. In metalydite, jarosite forms granular aggregates with small
tabular to pseudocubic crystals, occurring as pseudomorphs after pyrite or as crystals
within muscovite interlayers. Pyrite was not preserved in the studied metalydite as it was
completely replaced by secondary jarosite. Pyrite is present as an accessory mineral in the
accompanying graphitic-muscovite phyllites, locally in the metalydite. The sulphur necessary
for jarosite formation comes from the breakdown of pyrite, while the source of potassium
is muscovite. During the supergene process, low pH fluids attack muscovite, releasing K+
needed for jarosite formation. Chemical composition investigated by EPMA and based on
the Raman spectroscopy showed that, jarosite is typical with dominant Fe3+ in the interval
of 2.86–2.97 apfu and K+ in the range of 0.76–0.94 apfu. It contains minor amounts of Na+
up to 0.13 apfu, H3O+ up to 0.11 apfu, As5+ up to 0.08 apfu and Pb2+ up to 0.01 apfu. The
source of sodium in the jarosite is probably derived from muscovite, as no feldspars or clay
minerals have been identified in the metalydite. The arsenic in the jarosite is probably sourced
from arsenic-rich pyrite, while the source of lead may be attributed to galena, related
to hydrothermal processes within nearby metamorphic manganese mineralization. The
phosphorus in the jarosite likely originates from accessory apatite, which is found within
the surrounding acidic metavolcanoclastics and phyllites that host the metalydite horizons.
jarosit, chemické zloženie, metalydit, Západné Karpaty, Slovenská republika
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